X-RAY CRYSTAL STRUCTURE OF 1-METHYL-EXO, EXO-3,5-DICHLORO-8-THIATRICYCLO[2.2.1.1^2,6]-OCTANE TETRAFLUOROBORATE

A. L. Rheingold Department of Chemistry, University of Delaware, Newark, Delaware, 19716

E. J. Miller Department of Chemistry, University of Delaware, Newark, Delaware, 19716

R. L. Durney Department of Chemistry, University of Delaware, Newark, Delaware, 19716

R. L. Caret Department of Chemistry, Towson State University, Towson, Maryland, 21204

J. J. Uebel Eastman Kodak Company, Research Laboratories, Rochester, New York, 14650

Abstract

The synthesis and characterization by X-ray crystallography of the 1-methyl-exo, exo-3,5-dichloro-8-thiatricyclo[2.2.1.1.^2,6]octane cation (II) is described. Compound II is prepared from the reaction of exo, exo-3,5-dichloro-8-thiatricyclo[2.2.1.1.^2,6]octane (I) with trimethyloxonium tetrafluoroborate in nitromethane. Crystals of (II) belong to the space group, Pbca, with cell dimensions (298°K) of a=9.269(2) Å, b=12.112(3) Å, c=2.418(4) Å, V=2404.7(8) Å³, (Z=8. Solution and refinement of the intensity data gave final residuals of R_F =5.60% and R_w =6.26% using 1289 unique reflections with (F₀) > 3[sgrave] (F₀).

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X-RAY CRYSTAL STRUCTURE OF 1-METHYL-EXO, EXO-3,5-DICHLORO-8-THIATRICYCLO[2.2.1.1^2,6]-OCTANE TETRAFLUOROBORATE

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X-RAY CRYSTAL STRUCTURE OF 1-METHYL-EXO, EXO-3,5-DICHLORO-8-THIATRICYCLO[2.2.1.12,6]-OCTANE TETRAFLUOROBORATE

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X-RAY CRYSTAL STRUCTURE OF 1-METHYL-EXO, EXO-3,5-DICHLORO-8-THIATRICYCLO[2.2.1.1^2,6]-OCTANE TETRAFLUOROBORATE