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Original Articles

KOORDINATIONSVERBINDUNGEN OLIGOMERER THIOALDEHYDE MIT TITANTETRACHLORID

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Pages 21-24 | Received 04 Apr 1985, Published online: 13 Dec 2006
 

Abstract

The coordinative behaviour of the “weak bases” trimeric, tetrameric, and pentameric thioformaldehyde as well as trimeric thioacetaldehyde is studied towards the “hard acid” titaniumtetrachloride. The adducts (CH2S)3 · TiCl4, 1, (CH2S)4 · TiCl4, 2, (CH2S)5 · TiCl4, 3, 2(CH2S)3 · TiCl4, 4, 2(CH2S)4 · TiCl4, 5, 2(CH2S)2 · TiCl4, 6, and (CH3CHS)3 · TiCl4, 7, have been synthesized.

Das Komplexbildungsvermögen der “weichen Basen” trimerer, tetramerer und pentamerer Thioformaldehyd sowie trimerer Thioazetaldehyd gegenüber der “harten Säure” Titantetrachlorid wird untersucht. Die Addukte (CH2S)3 · TiCl4, 1, (CH2S)4 · TiCl4, 2, (CH2S)5 · TiCl4, 3, 2(CH2S)3 · TiCl4, 4, 2(CH2S)4 · TiCl4, 5, 2(CH2S)5TiCl4, 6, und (CH3CHS)3 · TiCl4, 7, werden beschrieben.

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