Advanced search
Publication Cover
Phosphorus and Sulfur and the Related Elements Volume 28, 1986 - Issue 1-2
Journal homepage
9
Views
4
CrossRef citations to date
0
Altmetric
Original Articles

AN INVESTIGATION OF THE REACTION PRODUCTS OF N3P3CL4(NH2)2 WITH NUCLEOPHILIC REAGENTS. EXAMPLES OF GEMINAL → NON-GEMINAL REARRANGEMENTS

John K. Fincham Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.
,
Michael B. Hursthouse Department of Chemistry, Queen Mary College (University of London), Mile End Road, London, E1 4NS, U.K.
,
Harold G. Parkes Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.
,
Leyl[acaron] S. Shaw (Née Gözen) Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.; Department of Chemistry, Queen Mary College (University of London), Mile End Road, London, E1 4NS, U.K.
&
Robert A. Shaw Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.
Pages 185-194 | Published online: 13 Dec 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Based on its reactions with various nucleophiles both geminal and non-geminal structures have been earlier proposed for N3P3Cl4(NH2)2, although its geminal structure is now considered established. The reactions of this compound with alcohols have been investigated and the products examined by NMR spectroscopy and X-ray crystallography. Evidence for both unrearranged as well as geminal → non-geminal rearranged alcoholysis products is presented.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.