SYNTHETIC, N.M.R. SPECTROSCOPIC AND X-RAY CRYSTALLOGRAPHIC INVESTIGATIONS ON THE PRODUCTS OF THE REACTIONS OF PHENYL (METHYL) PHOSPHONOTHIOIC DICHLORIDE AND THIOPHOSPHORYL CHLORIDE AND PSCL₃ WITH PRIMARY AMINES

Michael B. Hursthouse Department of Chemistry, Queen Mary College, (University of London), Mile End Road, London, E1 4NS, U.K.

Ezzeldine H. Ibrahim Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.; Department of Chemistry, Faculty of Science, Qatar University, Doha, Qatar

Harold G. Parkes Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.

Leyl[acaron] S. Shaw (Née Gözen) Department of Chemistry, Queen Mary College, (University of London), Mile End Road, London, E1 4NS, U.K.; Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.

Robert A. Shaw Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.

David A. Watkins Department of Chemistry, Birkbeck College (University of London), Malet Street, London, WC1E 7HX, U.K.

Abstract

The syntheses in solution of (i) 2,4-dialkylamino-, (ii) 2,4-dimethyl-, and (iii) 2,4-diphenyl-2,4-dithio-cyclodiphosph(V)azanes, [R′P(S)NR]₂ (R′ = NHR, Ph, or Me; R = alkyl), derived from thiophosphoryl trichloride, methylphosphonothioic and phenylphosphonothioic dichlorides and primary alkylamines are described. N.m.r. spectroscopic properties for these cyclodiphosph(V)azanes and their monomeric precursors, R′P(S)(NHR)₂ (R′ = NHR, Ph, or Me; R = alkyl), are presented and structural inferences are drawn from this data. The X-ray crystal structure of [PhP(S)NBuⁱ]₂ is reported.

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SYNTHETIC, N.M.R. SPECTROSCOPIC AND X-RAY CRYSTALLOGRAPHIC INVESTIGATIONS ON THE PRODUCTS OF THE REACTIONS OF PHENYL (METHYL) PHOSPHONOTHIOIC DICHLORIDE AND THIOPHOSPHORYL CHLORIDE AND PSCL₃ WITH PRIMARY AMINES

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SYNTHETIC, N.M.R. SPECTROSCOPIC AND X-RAY CRYSTALLOGRAPHIC INVESTIGATIONS ON THE PRODUCTS OF THE REACTIONS OF PHENYL (METHYL) PHOSPHONOTHIOIC DICHLORIDE AND THIOPHOSPHORYL CHLORIDE AND PSCL3 WITH PRIMARY AMINES

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SYNTHETIC, N.M.R. SPECTROSCOPIC AND X-RAY CRYSTALLOGRAPHIC INVESTIGATIONS ON THE PRODUCTS OF THE REACTIONS OF PHENYL (METHYL) PHOSPHONOTHIOIC DICHLORIDE AND THIOPHOSPHORYL CHLORIDE AND PSCL₃ WITH PRIMARY AMINES