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Original Articles

SELENIUM CONTENT OF NATURALLY OCCURRING ELEMENTAL SULFUR, OF INDUSTRIALLY PRODUCED SULFUR AND OF THE MINERAL SELENSULFUR1

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Pages 17-21 | Received 12 Feb 1986, Published online: 13 Dec 2006
 

Abstract

Nineteen samples of naturally occurring elemental sulfur or “selensulfur” were investigated by neutron activation analysis, Raman spectroscopy and high-pressure liquid chromatography. The natural sulfur samples contained between < 1 and 682 ppm selenium while nine industrially produced sulfur samples showed Se contents of ≤ 4 ppm. The existence of a mineral “selensulfur” consisting of only S and Se in comparable concentrations seems doubtful. Elemental sulfur minerals containing > 150 ppm Se were found to be yellow at 77 K while pure ordinary sulfur (α-S8) is colorless at this temperature.

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