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Phosphorus and Sulfur and the Related Elements Volume 31, 1987 - Issue 1-2
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Original Articles

DIBISYLDIPHOSPHENE: NEW ROUTES AND FIRST ASPECTS OF ITS REACTIVITY

Henri Ranaivonjatovo Laboratoire de Chimie des Organominéraux, U.A. du CNRS no 477, Université Paul Sabatier, Toulouse Cedex, France
,
Jean Escudié Laboratoire de Chimie des Organominéraux, U.A. du CNRS no 477, Université Paul Sabatier, Toulouse Cedex, France
,
Claude Couret Laboratoire de Chimie des Organominéraux, U.A. du CNRS no 477, Université Paul Sabatier, Toulouse Cedex, France
&
Jacques Satgé Laboratoire de Chimie des Organominéraux, U.A. du CNRS no 477, Université Paul Sabatier, Toulouse Cedex, France
Pages 81-87 | Received 07 Jul 1986, Published online: 03 Jan 2007
 
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Abstract

Dibisyldiphosphene, 1, one of the least crowded stable diphosphenes, has been obtained in high yield by two new routes starting with fluorophosphines. 1 dimerizes slowly at room temperature, reacts very easily with 2,3-dimethylbutadiene and cyclopentadiene to give cycloadducts 14 and 15, with selenium to form selenadiphosphirane 16, and is reduced by lithium aluminium hydride to give 18.

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Related Research Data

From 2,4-diphospha-3-thia- and -3-selenapentadienes [(Me3Si)2C=P]2E to heteronorbornane cage compounds.
Source: (:unav)
P-functional phosphaalkenes with C-isopropyldimethylsilyl groups, and a sterically stabilized P-cyano phosphaalkene
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Synthese, Struktur und Reaktivität von η3-1,2-Diphosphaallylkomplexen sowie von [{(η5-C5H5)(CO)2W–Co(CO)3}{μ-AsCH(SiMe3)2}(μ-CO)]
Source: Wiley
A Boryl‐Substituted Diphosphene: Synthesis, Structure, and Reaction with n‐Butyllithium To Form a Stabilized Adduct by pπ‐pπ Interaction
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Halogen(silyl)phosphane. Synthese und Eigenschaften
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