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Phosphorus and Sulfur and the Related Elements Volume 29, 1987 - Issue 2-4
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ELECTRON-TRANSFER PROCESSES. PART 40. REACTION OF ALKYL RADICALS WITH DIPHENYLPHOSPHIDE ANION

Glen A. Russell Department of Chemistry, Iowa State University, Ames, Iowa, 50011
&
Rajive K. Khanna Department of Chemistry, Iowa State University, Ames, Iowa, 50011
Pages 271-274 | Received 06 Jan 1986, Accepted 02 Jun 1986, Published online: 24 Feb 2007
 
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Abstract

The anion Ph2P− (K+, 18-crown-6) reacts with t-BuHgCl in HMPA to form Ph2PCMe3 by a free radical chain mechanism. In Me2SO, Ph2P(O)CMe3 is produced. Reaction of Ph2P− with PhCOCH2HgCl yields the oxidative dimerization product isolable from HMPA but readily converted to Ph2P(O)P(O)Ph2 in Me2SO.

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