SYNTHESE ET REACTIVITE D'UN ESTER CYCLIQUE D'α-AMINODIPHOSPHONATE. II

R. Burgada Laboratoire de Chimie des Organo-éléments, tour 44–45 Université P. & M. Curie, 4 place Jussieu 75252, Paris Cédex, 05

D. El Manouni Laboratoire de Chimie des Organo-éléments, tour 44–45 Université P. & M. Curie, 4 place Jussieu 75252, Paris Cédex, 05

A. Tromelin Laboratoire de Chimie des Organo-éléments, tour 44–45 Université P. & M. Curie, 4 place Jussieu 75252, Paris Cédex, 05

H. Fauduet Laboratoire de Chimie des Organo-éléments, tour 44–45 Université P. & M. Curie, 4 place Jussieu 75252, Paris Cédex, 05

Abstract

The reactions of methoxy dioxaphospholan and corresponding hydrogen phosphonate 1 with (MeN = CHCl)Cl, (MeO)₂CHNMe₂ and MeOCH₂NMe₂ have been studied.

These reactions lead either to amino diphosphonate 5 or to amino phosphonate 3 and phosphate 2. The hydrolysis and methanolysis reactions of 5 are also presented.

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SYNTHESE ET REACTIVITE D'UN ESTER CYCLIQUE D'α-AMINODIPHOSPHONATE. II

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SYNTHESE ET REACTIVITE D'UN ESTER CYCLIQUE D'α-AMINODIPHOSPHONATE. II

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