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Phosphorus and Sulfur and the Related Elements Volume 29, 1987 - Issue 2-4
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Communication

Ozonization: An Efficient Method for the Oxidation of Halophosphines

Anne-Marie Caminade Laboratoire Synthèse, Structure et Réactivité de Molécules Phosphorées U.A. 454, Université Paul Sabatier, 31062, Toulouse Cédex, France
,
Fayez El Khatib Laboratoire Synthèse, Structure et Réactivité de Molécules Phosphorées U.A. 454, Université Paul Sabatier, 31062, Toulouse Cédex, France
,
Antoine Baceiredo Laboratoire de Chimie des Organominéraux-U.A. 477, Université Paul Sabatier, 31062, Toulouse Cédex, France
&
Max Koenig Laboratoire Synthèse, Structure et Réactivité de Molécules Phosphorées U.A. 454, Université Paul Sabatier, 31062, Toulouse Cédex, France
Pages 365-367 | Received 14 Jan 1986, Accepted 12 Feb 1986, Published online: 24 Feb 2007
 
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Abstract

The ozonization of various halophosphines 1a-j leads with quantitative yields to the corresponding phosphine oxides 2a-j.

Ozonization is a convenient method of oxidation, in particular of compounds with bulky ligands (1c, 1d, 1e).

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