Abstract
Several novel phosphoranides with one or two organo-groups attached to phosphorus and no cyano-groups present have been synthesised for the first time, and identified in solution by 31P N.M.R. spectroscopy. Most of the complexes have been isolated, and further characterised by elemental analysis. Similar ionic derivatives were formed, as expected, by C6F5P(CN)2 and (C6F5)2P(CN).