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Phosphorus and Sulfur and the Related Elements Volume 30, 1987 - Issue 1-2
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Original Articles

Me5C5: A Versatile Ligand in Phosphorus Chemistry

Peter Jutzi Fakultät für Chemie der Universität Bielefeld, Universitätsstraße, D-4800, Bielefeld 1, F.R.G.
,
Hartmut Saleske Fakultät für Chemie der Universität Bielefeld, Universitätsstraße, D-4800, Bielefeld 1, F.R.G.
&
Udo Meyer Fakultät für Chemie der Universität Bielefeld, Universitätsstraße, D-4800, Bielefeld 1, F.R.G.
Pages 161-164 | Published online: 03 Jan 2007
 
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Abstract

Pentamethylcyclopentadienyl (pcp) phosphorus compounds with coordination number 2, 3, and 4 at phosphorus are described concentrating on their differing fluxional behavior (sigmatropic rearrangements). The pcp-substituted diphos-phene allows for the first time a substitution chemistry at the P=P unit.

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