The Quest for Metaphosphate Species. Phosphoric Chlorides and Anhydrides as Reactive Precursors

S. Cocks Department of Organic Chemistry, University of Cape Town, South Africa

J. Symes Department of Organic Chemistry, University of Cape Town, South Africa

T. A. Modro Department of Organic Chemistry, University of Cape Town, South Africa

Abstract

(β-Arylethyl)phosphorochloridates decompose easily yielding 1-chloro-2-arylethanes via the concerted P-Cl fission and the expulsion of metaphosphate species. Mixed anhydrides derived from carboxylic and amidophosphoric acids undergo unimolecular fragmentation to carboxyamides and metaphosphate esters.

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The Quest for Metaphosphate Species. Phosphoric Chlorides and Anhydrides as Reactive Precursors

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