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Phosphorus and Sulfur and the Related Elements Volume 30, 1987 - Issue 1-2
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Original Articles

Peracid and Acyl Peroxy Radical Mediated Oxidation and Rearrangement of Phosphoramides

R. Stephen Davidson Department of Chemistry, The City University, Northampton Square EClV OHB, London
&
Martin D. Walker Department of Chemistry, The City University, Northampton Square EClV OHB, London
Pages 305-310 | Published online: 03 Jan 2007
 
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Abstract

Acyl peroxy radicals can cause oxidation of sulphur at pentavalent phosphorus and can also affect the decomposition of phosphoramides. Peracids can also oxidise thiophosphorus compounds to their respective oxidised phosphorus analogues and oxidise phosphoramides via N-oxidation.

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