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Original Articles

Reactions of Phosphorus-Phosphorus Bonded Mixed-Valence Diphosphorus Compounds

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Pages 499-502 | Published online: 03 Jan 2007
 

Abstract

A novel type of mixed valence diphosphorus compound, involving the grouping Cl-P(-)-P(+)-NEt2, with the two phosphorus atoms doubly bridged by N.N'-dimethylurea, has become readily available. Reactions of this type of compound have furnished a variety of new structural elements, involving two directly bonded phosphorus atoms in two different oxidation states and / or coordination numbers.

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