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Original Articles

STUDY OF THE ALKALINE CLEAVAGE OF THE P[sbnd]C BOND IN PHOSPHINE OXIDES AND DERIVATIVES OF TRICHLOROMETHANEPHOSPHONATE

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Pages 141-152 | Received 07 Mar 1988, Published online: 13 Dec 2006
 

Abstract

A study of alkaline decomposition of several aromatic phosphine oxides containing p- and o-nitrobenzyl, and trichloromethyl as leaving groups, is reported. The property of the trichloromethyl group as leaving group, and the CCl 3-group's further decomposition in the hydrolysis of diethyl and disodium trichloromethanephosphonates, have also been investigated.

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