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Original Articles

REACTION OF SALTS OF HYPOPHOSPHOROUS ACID WITH ALKYLHALIDES

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Pages 261-265 | Received 16 Jun 1987, Accepted 27 Jul 1987, Published online: 19 Dec 2006
 

Abstract

Alkali salts of hypophosphorous acid undergo an exchange reaction with alkyl halides. From the interaction between potassium hypophosphite and allyl bromide or 3-chloro-1,2-propanediol phosphonous acids are formed. A mechanism of the interaction, a variant of the Michaelis-Becker reaction, is proposed.

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