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Phosphorus and Sulfur and the Related Elements Volume 35, 1988 - Issue 3-4
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Original Articles

UNUSUAL DIRECTION OF THE ARBUZOV REACTION OF DIALKOXYMETHYLPHOSPHONITES AND THEIR ANALOGUES

I. F. Lutsenko M. V. Lomonosov Moscow State University, Chemistry Department, 119899, Moscow, V-234, USSR
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A. A. Prishchenko M. V. Lomonosov Moscow State University, Chemistry Department, 119899, Moscow, V-234, USSR
&
M. V. Livantsov M. V. Lomonosov Moscow State University, Chemistry Department, 119899, Moscow, V-234, USSR
Pages 329-334 | Received 23 Mar 1987, Accepted 12 Jun 1987, Published online: 19 Dec 2006
 
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Abstract

The alkylation and acylation reactions of dialkoxymethylphosphonites and their analogues have been studied. The Arbuzov rearrangement of these compounds was accompanied by the P[sbnd]C bond cleavage with retention of three-coordinate phosphorus atom.

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