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Original Articles

SYNTHESE VON BIS(ALKYLTRITHIOCARBONATO)ORGANYLUND MONO(ALKYLTRITHIOCARBONATO)-DIORGANYL-PHOSPHANEN

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Pages 93-98 | Received 20 May 1987, Published online: 25 Feb 2007
 

Abstract

Compounds of the type RP(S2CSR′)2 with R=CH3, C(CH3)3, C6H5 and of the type R2PS2CSR′ with R=C(CH3)3, C6H5; R'=C2H5, CH(CH3)2 are obtained by reaction of organylchlorophosphanes with sodium alkyl trithiocarbonates. Ir, NMR and mass spectra have been assigned.

Durch Umsetzung der jeweiligen Organylchlorophosphane mit den entsprechenden Natri-umalkyltrithiocarbonaten erhält man Verbindungen des Typs RP(S2CSR′)2 mit R=CH3, C(CH3)3, C6H5 sowie Verbindungen des Typs R2PS2CSR′ mit R=C(CH3)3, C6H5; R'=C2H5, CH(CH3)2. IR-und NMR-Spektren sowie Massenspektren wurden zugeordnet.

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