Solubility and adsorption behaviors of chlorpyriphos-methyl in the presence of surfactants

Abstract

In the present work changes in the adsorption of the pesticide chlorpyrifos-methyl (CLP-m) on soil colloids induced by application of surfactants were determined using a batch equilibrium method. The surfactants used were sodium dodecyl sulphate (SDS), Tween 20, and dihexadecyldimethylammonium bromide (DHAB). The adsorption isotherms of CLP-m in aqueous medium and in surfactant solutions at concentration equal to the critical micelle concentration (CMC) fitted the Freunlich adsorption equation generally with R² values greater than 0.96. While the addition of SDS and DHAB decreased the pesticide adsorption, the addition of Tween 20 increased the pesticide adsorption. The increases or decreases in the adsorption in the experiment revealed that the behavior of CLP-m in soil water-systems mainly depends on the type of surfactant. Moreover water solubility of CLP-m changes by the three surfactants below and above their CMC were studied. While the solubility of CLP-m was enhanced by SDS both below and above the CMC, the solubility of the pesticide was enhanced by DHAB only above the CMC. Tween 20 did not influence the solubility of CLP-m.

Keywords:

• Chlorpyrifos-methyl
• adsorption
• solubility
• sodium dodecyl sulphate (SDS)
• dihexadecyldimethylammonium bromide (DHAB)
• Tween 20

Notes

^a Initial CLP-m concentration = 0.5 mg L^{− 1}.

^b Initial CLP-m concentration = 3 mg L^{− 1}.

^a Initial CLP-m concentration = 0.5 mg L^{− 1}.

^b Initial CLP-m concentration = 3 mg L^{− 1}.