Adsorption of chlortetracycline in aquaculture wastewater by lanthanum modified multi-walled carbon nanotubes

Abstract

The lanthanum modified multi-walled carbon nanotubes (La-CNTs) prepared by an impregnation method were investigated for the adsorption of chlortetracycline (CTC) in aquaculture wastewater. The adsorbents were characterized by SEM, EDS, XRD and BET. The effects of some factors including La-containing impregnant concentration, adsorbent dosage, CTC adsorbate concentration, adsorption time, pH of the adsorbate solution and additional ions on the CTC adsorption by La-CNTs were investigated in detail, and the optimal adsorption conditions were determined. The adsorption kinetics obeyed the quasi-second-order kinetic model. The adsorption isotherms obeyed the Langmuir model and the fitted maximum capacity of La-CNTs for CTC adsorption was 55.3 mg/g.

Keywords:

• Adsorbent
• thermodynamics
• isotherm
• adsorption capacity
• kinetics

Data availability statement

All data, models, and code generated or used during the study appear in the submitted article.

Correction Statement

This article has been republished with minor changes. These changes do not impact the academic content of the article.

Additional information

Funding

This work was supported by the State Oceanic Administration People’s Republic of China (201305002), Liaoning Science and Technology Public Welfare Fund (20170002), Science Foundation of Department of Ocean and Fisheries of Liaoning Province (201733), Natural Science Foundation of Liaoning Province (201602097), and Department of Science and Technology of Liaoning (2016LD0105).