Relationship between B-site order and properties in Pb(B′B″)O₃ perovskites

C. A. Randall Materials Research Laboratory, Pennsylvania State University University Park, PA, 16802

A. S. Bhalla Materials Research Laboratory, Pennsylvania State University University Park, PA, 16802

T. R. Shrout Materials Research Laboratory, Pennsylvania State University University Park, PA, 16802

L. E. Cross Materials Research Laboratory, Pennsylvania State University University Park, PA, 16802

Abstract

A simple classification scheme is presented which essentially relates the scale of B-site cation order in complex lead based perovskites Pb(B′B″)O₃ with either normal ferroelectric (antiferroelectric) or relaxor ferroelectric behavior, as observed in these materials.

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Relationship between B-site order and properties in Pb(B′B″)O₃ perovskites

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Relationship between B-site order and properties in Pb(B′B″)O₃ perovskites