Synthetic Approach to Olguine: EPC¹ Preparation of Ethyl 6,7-Anhydro-4-O-Benzyl-2,3-Dideoxy-α-D-Altro-Oct-2-Eno-1,8-Dialdo-1,5-Pyranoside

Serafín Valverde Institute de. Quimica Orgánica General C.S.I.C., Juan de la. Cierva 3, 28006, Madrid, Spain

Manuel Martin-lomas Institute de. Quimica Orgánica General C.S.I.C., Juan de la. Cierva 3, 28006, Madrid, Spain

Bernardo Herradón Institute de. Quimica Orgánica General C.S.I.C., Juan de la. Cierva 3, 28006, Madrid, Spain

Abstract

(+)-Olguine (1) is a natural product isolated in our laboratory₂ from a non-classified species of the genus Hyptis. It shows antileukemic activity invitro₃. We are interested in the synthesis of olguine and related compounds (such as diastereomers) in order to test their physiological activity.

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Synthetic Approach to Olguine: EPC¹ Preparation of Ethyl 6,7-Anhydro-4-O-Benzyl-2,3-Dideoxy-α-D-Altro-Oct-2-Eno-1,8-Dialdo-1,5-Pyranoside

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Synthetic Approach to Olguine: EPC1 Preparation of Ethyl 6,7-Anhydro-4-O-Benzyl-2,3-Dideoxy-α-D-Altro-Oct-2-Eno-1,8-Dialdo-1,5-Pyranoside

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Synthetic Approach to Olguine: EPC¹ Preparation of Ethyl 6,7-Anhydro-4-O-Benzyl-2,3-Dideoxy-α-D-Altro-Oct-2-Eno-1,8-Dialdo-1,5-Pyranoside