Terminal Deoxy Hydroxyamino Sugars

Jean M. J. Tronchet Institute of Pharmaceutical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

Guido Zosimo-landolfo Institute of Pharmaceutical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

Nicoletta Bizzozero Institute of Pharmaceutical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

Daniel Cabrini Institute of Pharmaceutical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

Ford Habashi Institute of Pharmaceutical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

Evelyne Jean Institute of Pharmaceutical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

Michel Geoffroy Department of Physical Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland

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Abstract

Reduction of sugar aldoximes gave in good yield the corresponding terminal deoxy hydroxyamino sugars. These compounds were found to be reasonably stable (they could be kept for some weeks at 4° C). On standing in the air, these compounds in solution were spontaneously oxidized to the corresponding nitroxide free radicals whose ESR spectra gave useful structural information.

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Terminal Deoxy Hydroxyamino Sugars

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Terminal Deoxy Hydroxyamino Sugars

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