Kinetics and Mechanism of the Oxidation of Some Aldoses by Cerium(IV)

Kalyan Kali Sen Gupta Department of Chemistry, Jadavpur University, Calcutta, 700 032, India

Shipra Sen Gupta Department of Chemistry, Jadavpur University, Calcutta, 700 032, India

Ambikesh Mahapatra Department of Chemistry, Jadavpur University, Calcutta, 700 032, India

Abstract

The kinetics of oxidation of some aldoses by cerium(IV) have been studied spectrophotometrically in sulphuric acid medium. The reactions are second order; first order with respect to both cerium(IV) and aldose concentration. The reaction rate decreases with increase in sulphuric acid concentration. The mechanisms for the reactions are discussed.

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Kinetics and Mechanism of the Oxidation of Some Aldoses by Cerium(IV)

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Kinetics and Mechanism of the Oxidation of Some Aldoses by Cerium(IV)

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