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ORIGINAL ARTICLES

Hydrogenolysis of Dioxolane-Type Diphenylmethylene Acetals by AlClH2 to Axial Diphenylmethyl Ethers

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Pages 191-200 | Received 06 Jan 1992, Published online: 27 Oct 2006
 

Abstract

A series of dioxolane-type diphenylmethylene acetals of pyranosides was converted into axial diphenylmethyl ethers in high yield using AlClH2 as the reducing agent. AlH3 did not cleave the acetals, AlCl2H regenerated both hydroxyl groups, and the intermediate diphenylmethyl ethers were also the substrates of this reagent.

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