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Nucleosides and Nucleotides Volume 10, 1991 - Issue 1-3: Proceedings of the 9th International Round Table
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Hydrogen Fluoride Mediated Alkylation and Dimerization of the Base Moiety of the cis Diastereoisomers of 5,6-Dihydroxy-5,6-dihydrothymidine

Michel Polverelli Laboratoires de Chimie, Département de Recherche Fondamentale, Centre d'Etudes Nucléaires de Grenoble, F-38041, GRENOBLE CEDEX, FRANCE
,
Maurice Berger Laboratoires de Chimie, Département de Recherche Fondamentale, Centre d'Etudes Nucléaires de Grenoble, F-38041, GRENOBLE CEDEX, FRANCE
&
Jean Cadet Laboratoires de Chimie, Département de Recherche Fondamentale, Centre d'Etudes Nucléaires de Grenoble, F-38041, GRENOBLE CEDEX, FRANCE
Pages 563-564 | Published online: 29 Aug 2007
 
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Abstract

Hydrolysis of the cis diastereoisomers of 5,6-dihydroxy-5,6-dihydrothymidine by hydrogen fluoride stabilized in pyridine in the presence of ethanol gives rise to the cis thymine glycol and the cis 6-ethooxy-5-hydroxy-5,6-dihydrothymine enantiomers.

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