Synthesis of 5-Formyluridines

Sidney D. Selvidge III Department of Chemistry, The University of Memphis, Memphis, Tennessee, 38152, U.S.A.

James Jang Department of Chemistry, The University of Memphis, Memphis, Tennessee, 38152, U.S.A.

Partha S. Ray Department of Chemistry, The University of Memphis, Memphis, Tennessee, 38152, U.S.A.

Abstract

5-Formyl-2′,3′-O-isopropylideneuridine and 5-formyl-2′,3′,5′-tri-O-acetyluridine were prepared by a new procedure involving palladium-catalyzed coupling of 5-iodouridine with styrene, followed by reaction with acetic anhydride or acetone and ozonolysis of the resulting 5-styryluridine derivatives.

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Synthesis of 5-Formyluridines

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Synthesis of 5-Formyluridines

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