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Abstract
A novel method of synthesis of 2′-deoxy-β-d-ribonucIeosides via transglycosylation of 6-oxopurine ribonucleosides is exemplified for conversion of inosine into 6-metylpurine 2′-deoxyriboside (5). The method offers high regio- and stereoselectivity as well as a good overall yield, and in these respects is superior to the fusion or anionic glycosylation procedures.
This paper is dedicated to Prof. Wolfgang Pfleiderer for the occasion of his 70th birthday.
Notes
This paper is dedicated to Prof. Wolfgang Pfleiderer for the occasion of his 70th birthday.
