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Original Articles

Thermodynamics of Nitric Acid Extraction with Iso-Butanol. I. Water Activity In Iso-Butanol

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Pages 271-282 | Published online: 22 Dec 2014
 

ABSTRACT

A numerical procedure was employed to evaluate hydrated water attached to the extractable nitric acid/iso-butanol complex. The hydratation number was found to be 11, a value favourable in comparison to the hydratation numbers published for straight chain alcohols extractants. Of several tested approaches, the fourth order interaction Scatchard equation offers water activity coefficients in the alcohol phase which are in close agreement with the measured ones.

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