Effects of drying temperature on hygroscopicity and mechanical performance of resin-impregnated wood

Abstract

To clarify the effects of drying temperature on the hygroscopicity and mechanical performance of MUF resin-impregnated wood, we investigated the water vapor adsorption capability, modulus of rupture (MOR), modulus of elasticity (MOE), and surface hardness of MUF resin-impregnated wood treated at 60, 80, 100, 120, 140 °C. Drying temperature can influence the hygroscopicity of MUF resin-impregnated wood. As temperature increased, hygroscopicity typically decreased, but the resin-impregnated wood hygroscopicity increased after treatment at 60 °C. Drying temperature has shown significant influence on the mechanical performance of MUF resin-impregnated wood (α = 0.01). Increasing the treatment temperature can enhance the mechanical performance of resin-impregnated wood. However, brittleness of the resin-impregnated wood increased after treatment at 140 °C. Characterization of FTIR and ¹³C CP/MAS NMR indicate that higher drying temperature led to lower content of hydroxymethyl groups and more substituted reactive sites on the amino group. This refers to more complete dehydration condensation between the resin active groups, thereby increasing the crosslinking density of the resin, increasing the cohesive strength, and decreasing the hygroscopic groups.

Keywords:

• MUF resin-modified wood
• DVS
• MOR
• MOE
• surface hardness
• resin curing

Acknowledgments

The authors are grateful for the support of the National Natural Science Foundation of China (31800479), Natural Science Foundation of Hunan Province (2020JJ5978), Scientific Research Foundation of Hunan Provincial Education Department (19B592), and Scientific Research Foundation of Central South University of Forestry and Technology (2019YJ015).

Disclosure of interest statement

The authors report no conflicts of interest. The authors alone are responsible for the content and writing of the paper.