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Original Articles

Low-Frequency Parametrization of Hydrogen Bonding

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Pages 1057-1067 | Received 19 Nov 1990, Published online: 21 May 2012
 

Abstract

We review the model of the hydrogen bond developed by Lippincott and Schroeder and discuss the frequency range in which it is valid, specifically in the optical and near infrared range. We then show why and how to modify the Lippincott and Schroeder formulae to apply to the far infrared and lower ranges. The contrasts between the old and modified systems, particularly with respect to the effective force constants are worked out and plotted for an example.

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