Abstract
Statistical comparisons of 2008 surface water quality data with a historical data set at weekly and subweekly resolution revealed statistically significant reductions in total phosphorus (TP) and a trend of reduction in dissolved phosphorus following implementation of a municipal ordinance limiting the application of lawn fertilizers containing phosphorus. No reductions were seen at an upstream control river site not affected by the ordinance. Nontarget analytes including nitrate, silica and colored dissolved organic matter did not change systematically as did P. The data were analyzed in the context of a statistical model that characterized historical temporal variability and predicted the sampling effort needed to detect changes of specified magnitude. Expected changes of about 25% in monthly mean value were predicted to require weekly samples during the summer for only 1 or 2 years for TP; statistically significant reductions measured after 1 year averaged 28%, or about 5 kg P/day. The lawn fertilizer ordinance was only one component of broader efforts to reduce nonpoint source loading of P, however, so the magnitude of its role in the measured changes remains uncertain.
Acknowledgments
This study was funded in part by U.S. EPA STAR grant R830653010, USDA CSREES 2006–02523, and the city of Ann Arbor. We thank E. Kenzie for providing daily discharge data for the AAWWTP.