The genesis of Pb‐Zn sulphide occurrences in the Lower Devonian Buchan Group, Victoria

Six minor sulphide occurrences hosted by the Lower Devonian Buchan Group have been investigated. Sulphide minerals and associated phases are hosted by both dolostone and limestone lithologies along stylolitized bedding planes, cross‐cutting fractures, low angle minor faults and in cavities. Mineralization was closely associated with minor structures of inferred Tabberabberan age (Middle Devonian), which it appears to have post‐dated, but was largely strata‐bound in nature. The mineralogy of the occurrences is simple and characterized by the following generalized paragenesis which reflects the increasing oxidation state and pH of the mineralizing fluids: pyrite (pseudomorphous after marcasite)‐galena ± sphalerite ± pyrite‐dolomite ± barite‐calcite ± fluorite ± dolomite.

The sulphur isotope composition of sulphide minerals varies from ‐32.1 to +4.1‰, with iron and base metal sulphide minerals forming two distinct populations around ‐25‰ and 0‰, respectively. A single barite sample gives a sulphur isotope composition of +22.4‰, which is similar to that estimated for Early Devonian seawater. Fluid inclusions in fluorite and calcite homogenize at temperatures in the range 160 to 212° C and have average salinities of approximately 10 wt% NaCI eq. Sphalerite contains up to 1.81 wt% iron which correlates with colour, and up to 1.43 wt% cadmium. The Pb isotopic pattern of galena suggests a source region with U/Pb(= μ) lower than the crustal average, and a high Th/U.

A genetic hypothesis is proposed which involves the circulation of saline fluids through the Snowy River Volcanics, which directly underlie the Buchan Group, during or at some time after the Tabberabberan Orogeny. Although the Buchan occurrences show features characteristic of both Mississippi Valley‐type and stratiform ore deposits, they are most directly comparable to the epigenetic zones of Irish carbonate‐hosted base‐metal deposits. However, Pb‐Zn sulphide mineralization at Buchan appears to have been associated with minor compressional structures, suggesting that a simple correlation with the Irish deposits is not directly applicable.

Key words:

• Buchan Group
• Devonian
• ore genesis
• Pb‐Zn sulphide minerals

Notes

Present address: Department of Earth Sciences, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 3J5.

Present address: BHP Iron Ore, PO Box 655, Newman, WA 6753, Australia.