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ABSTRACT
Porphyry copper and mixed copper-gold sulfide deposits contain varying amounts of precious (gold and silver) and platinum group metals (PGMs). Currently, milling and froth flotation is the most common processing route for the treatment of high-grade base metal sulfide ores. During this process, the precious metals and PGMs are also concentrated and represent a possible opportunity for the beneficiation of these metals to increase the overall economic value of the ore. Although not yet commercialized, the high temperature pressure oxidation (POX) of copper concentrates provides an alternative processing route to traditional smelting technology. With increasingly aggressive air quality standards and rising upstream processing costs for smelting, hydrometallurgical processing options become progressively attractive. The treatment of POX residues for the recovery of precious metals has seen significant attention and multiple processing routes have been developed on various scales. Extraction and beneficiation of PGMs from copper concentrate POX residue has garnered significantly less attention and mechanistic questions remain to be answered. Based on a review of the processing options for PGM ores and concentrates, hydrometallurgical processing routes for the extraction of PGMs from copper concentrate POX residues are envisioned.