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Original Articles

Adsorption of Octyl Hydroxamic Acid/Salt on Cassiterite

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Pages 503-519 | Received 30 Nov 1998, Accepted 08 Nov 1999, Published online: 22 Dec 2010
 

Abstract

The interaction of octyl hydroxamic acid/salt with cassiterite has been studied using adsorption, electrokinetic and infrared spectroscopic techniques. Results indicate that the surfactant sorbs on the mineral surface by relatively weak forces, both specific and physical in nature. Adsorption was greater in the acidic pH region than in the alkaline pH, implying the involvement of hydroxamic acid molecule and hydroxylated cassiterite of the type-Sn(OH), in the sorption process. Electrokinetic and FTIR studies confirmed the involvement of specific forces of interaction in the sorption process. Based on the experimental observations, the possible modes of sorption are discussed.

Additional information

Notes on contributors

T. SREENIVAS

e-mail: [email protected]

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