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Abstract
Auxetic materials (i.e. materials with a negative Poisson's ratio) expand laterally when stretched and become thinner when compressed. This unusual yet very useful property arises from the way by which the nano or microstructure of the material deforms when subjected to uniaxial mechanical loads. This paper discusses a novel class of molecular-level auxetic (networked polymers) built from calix[4]arene building blocks. These calix[4]arene subunits are connected in such a way that they mimic the shape of a “folded macrostructure” which is known to exhibit auxetic behaviour. We confirm through force-field based simulations that these newly proposed networked polymers exhibit negative Poisson's ratios, the magnitudes of which can be changed by introducing slight variations in the molecular structure of these polymers. We also develop simple geometry-based models which explain the values of the Poisson's ratios obtained through the force-field based simulations, and which give an insight into the features of the molecular structure that are responsible for the auxetic effect.
Acknowledgements
We would like to thank Mr Brian Spiteri, Miss Lara Trapani and Mr Victor Zammit of the University of Malta for their contribution to this work.
