Publication Cover
High Pressure Research
An International Journal
Volume 16, 2000 - Issue 5-6
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Original Articles

A new global hydrogen equation of state model

Pages 389-400 | Received 01 Apr 1999, Accepted 01 Aug 1999, Published online: 19 Aug 2006
 

Abstract

Simple statistical mechanics models have been assembled into a wide-range equation of state for the hydrogen isotopes. The solid is represented by an Einstein-Grüneisen model delimited by a Lindemann melting curve. The fluid is represented by an ideal gas plus a soft-sphere fluid configurational term. Dissociation and ionization are approximated by modifying the ideal gas chemical-equilibrium formulation. The T = 0 isotherm and dissociation models have been fitted to a new diamond-anvil isotherm and to laser-generated shock data. The main limitation of the model is in ionization at high compression.

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