Publication Cover
High Pressure Research
An International Journal
Volume 20, 2001 - Issue 1-6
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Original Articles

Hydrothermal synthesis of an iron(II) dicarboxylate

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Pages 99-107 | Received 10 Jan 2000, Accepted 25 Feb 2000, Published online: 19 Aug 2006
 

Abstract

A new Fe(II) succinate (1) was synthesized in an autogenous pressure by a hydrothermal reaction. The crystal structure was determined by single crystal X-ray diffraction analysis. The prepared Fe5(OH)2(C4H4O4)4 crystallizes in a monoclinic unit cell with the dimensions of a = 9.489(2)Å, b = 9.429(3, c = 12.487(2)Å, β=96.77(1)° and space group of P21/c (No. 14). The oxygens of succinate coordinate iron(II) with edge-sharing octahedra to form three dimensional network. The oxidation state iron has been confirmed by valence sum calculation as well as by the room temperature magnetic susceptibility. At room temperature Fe(II)(3d6) shows high spin state with paramagnetic behavior.

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