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High Pressure Research
An International Journal
Volume 23, 2003 - Issue 3: PROCEEDINGS OF THE XXXX EUROPEAN HIGH PRESSURE RESEARCH GROUP MEETING ON ADVANCES ON HIGH PRESSURE RESEARCH (EHPRG'40)
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THEORETICAL AND EXPERIMENTAL STUDIES OF PHASES AND PHASE TRANSITIONS

EXTERNAL PRESSURE AND LIGHT INFLUENCE ON INTERNAL PRESSURE IN A SPIN-CROSSOVER SOLID [Zn:Fe(ptz)6](BF4)2

Jelena Jeftić University of Rennes, ENSCR UMR CNRS 6052, Avenue du General Leclerc, 35700, Rennes, FranceCorrespondence[email protected]
,
Claude Ecolivet University ofRennes 1, GMCM Bat. 11 A, Campus de Beauliett, 35042, Rennes cedex, France
&
Andreas Hauser University of Geneva, Sciences II, 30, quai Ernest-Ansermet, 1211, Geneve, Suisse
Pages 359-363 | Received 12 Sep 2002, Published online: 06 Sep 2010
 
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Abstract

The relation between the internal pressure during spin-crossover is compared to the chemical pressure induced by dilution with zinc. Further, the light of a specific LIESST (Light Induced Excited Spin State Trapping) wavelength is used to induce partial stabilisation of high-spin state and thus shift temperature of the spin-crossover towards lower values. The de-coupling of the spin-crossover and structural phase transition is discussed.

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