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High Pressure Research
An International Journal
Volume 23, 2003 - Issue 3: PROCEEDINGS OF THE XXXX EUROPEAN HIGH PRESSURE RESEARCH GROUP MEETING ON ADVANCES ON HIGH PRESSURE RESEARCH (EHPRG'40)
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CHEMICAL REACTIONS AND KINETICS

MEASURED SOUND VELOCITIES OF H2O AND CH3OH

J. M. Zaug University of California, Lawrence Livermore National Labomiory, Livermore, California, 94550, USACorrespondence[email protected]
,
L. E. Fried University of California, Lawrence Livermore National Labomiory, Livermore, California, 94550, USA
,
E. H. Abramson Department of Chemistry, University of Washington, Seattle, Washington, 98195
,
D. W. Hansen University of California, Lawrence Livermore National Labomiory, Livermore, California, 94550, USA
,
J. C. Crowhurst University of California, Lawrence Livermore National Labomiory, Livermore, California, 94550, USA
&
W. M. Howard University of California, Lawrence Livermore National Labomiory, Livermore, California, 94550, USA
Pages 229-233 | Received 02 Sep 2002, Published online: 06 Sep 2010
 
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Abstract

We present sound velocity results from impulsively stimulated light scattering (ISLS) experiments conducted in diamond anvil cells on pure supercritical fluids. We have made measurements on fluid H2O (water), and CH3OH (methanol). Sound speeds measured through ISLS have allowed us to refine existing potential models used in the exponential-6 (EXP-6) detonation product library [L, E. Fried and W. M. Howard, J. Chem. Phys., 109(17), 7338-7348 (1998).]. The refined models allow us to more accurately assess the chemical composition at the Chapman-Jouget (C-J) state of common energetic materials. We predict that water is present in appreciable quantities at the C-J state of energetic materials HMX, RDX, and nitro methane.

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