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High Pressure Research
An International Journal
Volume 16, 1999 - Issue 3
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Original Articles

Neutron scattering investigation of ice under hydrostatic helium pressure

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Pages 201-214 | Received 24 Nov 1997, Accepted 26 Aug 1998, Published online: 19 Aug 2006
 

Abstract

Results of the inelastic incoherent neutron scattering investigations of water and ice in the 273–114K temperature interval under hydrostatic helium pressures up to 300 MPa are presented. It is shown that ice III is not formed in the process of isobaric cooling, but at about 239 K, a helium clathrate crystallizes. Its inelastic incoherent neutron scattering spectrum is close to that of ice II and this phase evidently is a solid solution of helium in ice II, in conformity with the results of a neutron diffraction study by D. Londono, et al. The position of the low-energy cutoff of the librational band follows the regularity found earlier for the dependence of the generalized phonon density of states on density of high pressure phases of pure ice.

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