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Original Articles

The potential for ordered grain boundary sliding in nanocrystalline palladium

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Pages 343-351 | Received 17 Jul 2007, Accepted 21 Feb 2008, Published online: 12 May 2008
 

Abstract

In nanocrystalline (nc) materials, the misfit of lattice structures at the junctions of grain boundaries (GBs) generally increases local stresses that can be released by GB sliding. In this article, the sliding behaviors of the ordered Σ = 3 (111) GB (twin) and Σ = 11(113) GB in nc palladium have been investigated by means of high-resolution transmission electron microscopy observations and molecular statics calculations. It is found that the twin boundary (TB) can release either large stresses by sliding with a DSC-lattice vector of 1/6 or small stresses by sliding over an imperfect vector. The observed Σ = 11 GB image is exactly symmetrical from which we can clearly identify no GB sliding along the [332] direction, but we cannot determine a sliding component along the direction. The image simulations indicate that the latter is experimentally unidentifiable.

Acknowledgements

The work is supported by the Natural Science Foundation of China (NSFC) (Nos 50471080 and 50571100) and National Basic Research Program of China (No. 2006CB605103).

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