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Original Articles

Hydrothermal synthesis and characterization of CaSO4 pseudomicrorods

, , , &
Pages 289-298 | Received 08 Jun 2009, Accepted 04 Jan 2010, Published online: 30 Mar 2010
 

Abstract

Calcium sulphate (CaSO4) pseudomicrorods have been synthesized by a low-temperature hydrothermal method using CaSO4 powder as a precursor and hexadecylamine as a surfactant at 180°C for at different intervals of time. The powder X-ray diffraction pattern indicates that the as-formed pseudomicrorods are of orthorhombic phase with lattice parameters a = 7.0023(4) Å, b = 6.9939(5) Å and c = 6.2434(4) Å. Scanning electron microscopy images show that the pseudomicrorods have diameters of about 0.2–2.5 µm and lengths of about 2–10 µm. Fourier transform infrared spectroscopy shows a strong doublet near 609 and 681 cm−1 arising from ν4 bending vibrations. The strongest band observed at 1132 cm−1 is associated with ν3 stretching vibrations. The band near 420–450 cm−1 is attributed to ν2 bending vibrations. The Raman spectrum exhibits an intense peak at 1008 cm−1 associated with the mode. The photoluminescence spectrum exhibits UV bands (330, 350 nm), strong green bands (402, 436 nm) and weak blue bands (503 nm). A widening of the optical band gap was observed as the particle size decreased.

Acknowledgements

HN thanks Dr. S.C. Sharma, Vice Chancellor, Tumkur University, Tumkur for the constant support and encouragement, also thanks UGC for awarding a minor research project. RPSC thanks Dr. H.S. Maiti, Director CGCRI, and Dr. Ranjan Sen, Head of Glass Technology Laboratory CGCRI, for their constant support and encouragement.

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