Near-infrared transitions of LiNdP₄O₁₂ and LiErYP₄O₁₂

Abstract

Fluorescence transitions in LiNdP₄O₁₂: ⁴ F_3/2→⁴I_9/2 (0·90μm), ⁴F_3/2→⁴I_11/2 (1·05μm), ⁴F_3/2→⁴I_13/2 (1·32μm), ⁴F_3/2→⁴I_15/2 (1·77μm), and in LiErYP₄O₁₂: ⁴S_3/2→⁴I_11/2 (1·3μm), ⁴I_13/2→⁴I_15/2 (1·53μm), have been obtained at room temperature. The positions of the energy levels related to the excitation, nonradiative and radiative processes have been established from complementary absorption measurements. The fluorescence lifetimes of the above-mentioned transitions have been determined from single exponential decays.