The microstructure and plastic deformation behaviour of Al-rich Ti-Al single crystals containing 54.7 and 58.0 at.% Al have been examined, focusing on the effect of chemical ordering of a Al5Ti3 superstructure on anomalous strengthening. Fine precipitates with the Al5Ti3 superstructure were developed in the L10 matrix of the Ti-58.0 at.% Al alloy. The size and volume fraction of the precipitates varied depending on temperature. An anomalous increase in the yield stress of the two alloys appeared at around 800oC. This strengthening mechanism is discussed on the basis of the difference in antiphase-boundary energies on (111), (110) and (001) planes in the Al5Ti3 phase.
Stress anomaly in Al-rich Ti-Al single crystals deformed by the motion of 1/2«110] ordinary dislocations
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