E.S.R. Studies of Free Radicals Derived from Reaction of OH with Uracil and Thymine: International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine: Vol 38, No 6

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Summary

Short-lived free radicals produced in N₂O-saturated aqueous solutions of uracil and thymine have been studied using the in situ radiolysis steady-state e.s.r. method. Radicals formed in alkaline aqueous solutions by OH addition to either positions C(5) or C(6) were observed. Mechanisms for the formation of transient species were derived. The spin density distribution of the unpaired electron was calculated by means of the INDO method.

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E.S.R. Studies of Free Radicals Derived from Reaction of OH with Uracil and Thymine

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E.S.R. Studies of Free Radicals Derived from Reaction of OH with Uracil and Thymine

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