290
Views
16
CrossRef citations to date
0
Altmetric
Original Articles

Preliminary characterization of polycyclic aromatic hydrocarbons, nitrated polycyclic aromatic hydrocarbons and polychlorinated dibenzo-p-dioxins and furans in atmospheric PM10 of an urban and a remote area of Chile

, , &
Pages 809-820 | Received 25 Mar 2011, Accepted 10 Jun 2011, Published online: 18 Nov 2011
 

Abstract

The composition of particulate organic fraction was determined in atmospheric aerosols emitted in two sites of central and southern Chile. In particular, polycyclic aromatic hydrocarbons (PAHs), nitrated-PAHs (N-PAHs) and polychlorinated dibenzo-p-dioxins (PCDDs) and furans (PCDFs) were investigated in both the urban site of Concepcion and the remote site of Coyhaique. The sampling was carried out with an active device during March and April 2007, and organic compounds adsorbed in air particles, having an aerodynamic diameter lower than 10 μm (PM10), were characterized using gas chromatography coupled with mass spectrometric detection (GC-MS). Aerosol contents varied from 0.004 to 3.4 ng m−3 for PAH, from 0.007 to 3.5 pg m−3 for N-PAH, from 0.002 to 355.7 fg Nm−3 for PCDDs and from 0.04 to 15 fg Nm−3 for PCDFs. As expected, the lowest values were found in the remote area.

In Concepcion city, despite the low number of samples, PAH levels and diagnostic ratios of some marker compounds suggested the diesel emissions, probably coming from trucks, as the major source of particulate organic pollutants associated with direct emission. Another important source of atmospheric pollution in the urban site was likely represented by the steel industry existing in this area, outlined both by the analysis of PAH and PCDD/F levels. In the samples collected in the remote air of Coyhaique (located in the southern part of Chile), the concentration of pollutants characterized by a long lifetime, as PCDD/Fs, could be related to long-range transport phenomena, instead of local sources.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.