Experimental and statistical analysis of As(III) adsorption from contaminated water using activated red mud doped calcium-alginate beads

ABSTRACT

Arsenic present in water bodies causes devastating effects on aquatic organisms and indirectly poses a hazardous threat to human existence. There is an urgent need to develop potential and convincing technologies to troubleshoot this problem. In the present study, an adsorbent has been prepared using the waste red mud from hazardous aluminium industry and doping it with calcium-alginate beads (ARMCB) for the effective removal of As(III) from wastewater. The concentration of As(III) was reduced from 0.101 mg/L to 0.008 mg/L after adsorption which effectively met the economic and environmental conditions imposed by WHO (>0.01 mg/L). Further, the statistical Response Surface Methodology (RSM) is adopted to analyze the combined effects of four operational parameters namely: pH, sorbent dosage, contact time and initial concentration on the adsorption of As(III) from the synthetic contaminated water samples. A high correlation coefficient (R2) value of 0.9672 projected by ANOVA confirmed the satisfactory regression of the developed model. The maximum adsorption capacity is found to be 1.807 mg/g at optimum operating conditions. The surface characterization of the adsorbent before and after adsorption by SEM, EDX, XRD, and FTIR confirms the potentiality of the adsorbent towards As(III) ions. Thermodynamic, adsorption isotherms and kinetic analysis respectively projected the endothermic Langmuir model adsorption of As(III) and the pseudo-second-order rate kinetics of the sorption mechanism. The current study aids the implementation of the developed robust technique for the successful removal of As(III) from industrial and domestic polluted water samples.

GRAPHICAL ABSTRACT

KEYWORDS:

• Red Mud
• Arsenic(III)
• Statistical design
• response surface methodology
• robust adsorbent

Acknowledgement

The authors thank the Ministry of Environment & Forests (MOEF), New Delhi, for granting the project entitled ‘Red mud as an adsorbent for the removal of pollutants’ (19/16/2014-RE)

Disclosure statement

No potential conflict of interest was reported by the authors.

ORCID

G. Suresh Kumar http://orcid.org/0000-0003-3833-5482

G. V. Krishna Mohan http://orcid.org/0000-0003-4513-4400

Additional information

Funding

This work was supported by Ministry of Environment and Forests: [Grant Number 19/16.2014-RE].