Investigation of low-temperature performances of hybrid catalysts with different chain length OHC reductants

ABSTRACT

In the present work, NO_x conversion efficiency of the hybrid catalysts at low temperatures was investigated. ANP-TVM and ANP-TVC-TVM hybrid catalysts for OHC-SCR performance were prepared by the impregnation method. The properties of catalysts were characterized by scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) and X-ray diffraction (XRD) analyses. The NO_x conversion ratios with real diesel exhaust gases were performed using oxygenated hydrocarbon reductants such as ethanol, propanol, n-butanol and n-penthanol. Performances of the hybrid catalysts at different engine loads and low temperatures were investigated. It was determined that ANP-TVC-TVM gave better results at all temperatures and loads. In general, the performance of ANP-TVC-TVM hybrid catalyst was superior with ethanol reductant except for at 1 kW engine load. The maximum NO_x conversion ratio was 90.6% on the ANP-TVC-TVM hybrid catalyst with n-butanol at 1 kW engine load and 300°C.

GRAPHICAL ABSTRACT

KEYWORDS:

• NO_x
• OHC-SCR
• catalyst
• reductant
• diesel engine

Disclosure statement

No potential conflict of interest was reported by the author(s).