ABSTRACT
The smart magnetic nanocomposites have been doped to diminish the energy bandgap of the photocatalyst and to permit recovering of the photocatalyst after the wastewater treatment. The core–shell Fe3O4@TiO2 nanocomposite was synthesised by the hydrothermal method using titanium butoxide as a precursor. The nanocomposites were examined by XRD, VSM, UV-Vis, and TEM techniques. The energy band gap of core–shell Fe3O4@TiO2 nanocomposite is 3.5 eV. Doping of copper with a concentration of 1, 2, and 3 wt% into TiO2 shell was done to increase the performance of photocatalyst. The Fe3O4/PVP@TiO2@Cu photocatalyst was used for dye wastewater treatment. The energy bandgap decreased to 2.2 eV after copper doping into the TiO2 shell specified that copper-doped nanocomposite could be an outstanding photocatalyst. The photocatalytic activity was carried out using methylene blue(MB) and methyl orange (MO) under sunlight. About 65% of methylene blue and 85% of methyl orange degradation was done using Cu (3wt %) doped Fe3O4@TiO2 nanocomposite. These photocatalysts can be easily withdrawn with a magnetic field. The Fe3O4/PVP@TiO2@Cu photocatalyst has been demonstrated to be very functional or effective for the degradation of MB and MO dyes using solar illumination.
GRAPHICAL ABSTRACT
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Disclosure statement
No potential conflict of interest was reported by the author(s).
Data availability
The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.